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First-level organometallic chemistry topics

Our reseach focuses on the development of early-transition organometalic systems which are involved in the activation of small molecules. Particular enphasis is devoted to N2, although we have interest in other small molecules such as H2 or CO2 in order to synthesize high-value products. This research is of great value for our students, who do in-depth research and develop their expertise in synthesis, catalysis and spectroscopy during their internship in our group.

Click below to learn more about our research lines:

- Dinitrogen fixation, activation and functionalization.

- Organometallic catalysis.

- Redox active ligands.

- Reactivity of polymetallic complexes.


“Ti(III) Catalysts for CO2/Epoxide Copolymerization at Unusual Ambient Pressure Conditions”  I. Sancho, M. Navarro, M. Montilla, P. Salvador, C. Santamaría, J. M. Luis, A. Hernán-Gómez, Inorganic Chemistry. 2023, 62, 37, 14873–14887.

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“Reductive Hydrogenation of Sulfido-Bridged Tantalum Alkyl Complexes: A Mechanistic Insight”  J.J. Carbó, M. Gómez, C. Hernández-Prieto, A. Hernán-Gómez, A. Martín, M. Mena, J.Puiggalí-Jou, J.M. Ricart, C. Santamaría, Inorganic Chemistry. 2023, 62, 26, 10100-10109.

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“Monocyclopentadienyltitanium(III) Complexes with Hydridoborato Ligands” A. Calvo-Molina, E. del Horno, J. Jover, A. Pérez-Redondo, C. Yélamos,  R.Zapata, Organometallics. 2023, 42, 12, 1360-13-72

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“Dinitrogen Binding at a Trititanium Chloride Complex and Its Conversion to Ammonia under Ambient Conditions” E. del Horno, J.Jover, M. Mena, A.Pérez-Redondo, C. Yélamos-Ruiz, Angew. Chem.Int. Ed. 2022, 61, e202204544.

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Metallocubanes Research Group
Organic and Inorganic Chemistry Department, Pharmacy Faculty
University Campus, Crta. Madrid-Barcelona km 33.6
28805 - Alcalá de Henares, Madrid (Spain)

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