PUBLICATIONS

“Dinitrogen Binding at a Trititanium Chloride Complex and Its Conversion to Ammonia under Ambient Conditions” E. del Horno, J.Jover, M. Mena, A. Pérez-Redondo, C. Yélamos-Ruiz, Angew. Chem.Int. Ed. 2022, 61, e202204544.

DOI: 10.1002/anie.202204544 -- Link

“N=N Bond Cleavage by Tantalum Hydride Complexes: Mechanistic Insights and Reactivity.” E.Álvarez-Ruiz, J. Carbó, M. Gómez, C. Hernández-Prieto, A. Hernán-Gómez, A. Martín, M. Mena, J.Ricart, A. Salom-Català, C. Santamaría, Inorg Chem, 2022, 61, 474-485.

DOI: 10.1021/acs.inorgchem.1c03152 -- Link

"Low-Valent Titanium Species Stabilized with Aluminum/Boron Hydride Fragments” E. del Horno, J.Jover, M. Mena, A. Pérez-Redondo, C. Yélamos, Chem. Eur. J., 2022, 28, e202103085.

DOI: 10.1002/chem.202103085  -- Link

“Structural Diversity in the Reactions of Dimetallic Alkyl Titanium Oxides with Isonitriles and Nitriles” M. Gómez-Pantoja, J. I. González-Pérez, A. Martín, M. Mena, C. Santamaría, M. Temprado, Organometallics, 2021, 49, 2610-2623.

DOI: 10.1021/acs.organomet.1c00300 -- Link

“X-Ray Crystal Structures of Two Monopentamethylcyclopentadienylhafnium(IV) Complexes” M.Mena, A. Pérez-Redondo, V. Varela-Izquierdo, C. Yélamos, Crystallography Reports, 2021, 66,448-454.

DOI: 10.1134/S1063774521030184 -- Link

“Successive Protonation and Methylation of Bridging Imido and Nitrido Ligands at Titanium Complexes.” P. Barriopedro, J. Caballo, M. Mena, A. Pérez-Redondo, C. Yélamos, Inorg Chem,  2020,  59, 7631-7643.

DOI: 10.1021/acs.inorgchem.0c00550 -- Link

“Preparation of Dimeric Monopentamethylcyclopentadienyltitanium(III) Dihalides and Related Derivatives.” E. del Horno, R. Jiménez-Aparicio, M. Mena, A. Pérez-Redondo, J. L. Priego, C.Yélamos, Inorg Chem, 2020, 59, 3740-3752.

DOI: 10.1021/acs.inorgchem.9b03399 -- Link

“A Bridging bis-Allyl Titanium Complex: Mechanistic Insights into the Electronic Structure and Reactivity.” J. Carbó, M. Gómez-Pantoja, A. Martín, M. Mena, J. Ricart, A. Salom-Català, C.Santamaría, Inorg Chem, 2019, 58, 12157-12166.

DOI: 10.1021/acs.inorgchem.9b01505 -- Link

“Synthesis and Characterization of Cyclopentadienyl Sulfur Niobium Complexes.” M. Gómez, C.Hernández-Prieto, A. Martín, M. Mena, C. Santamaría, J. Organomet. Chem, 2019, 897, 148-154.

DOI: 10.1016/j.jorganchem.2019.06.022 -- Link

“Cyclopentadienyl yttrium complexes with the [{Ti(η⁵-C5Me5)(μ-NH)}3(μ³-N)] metalloligand” J.Caballo, M. Mena, A. Pérez-Redondo, C. Yélamos, J. Organomet. Chem, 2019, 896, 139-145.

DOI: 10.1016/j.jorganchem.2019.06.005 -- Link 

“Ammonia–Borane Derived BN Fragments Trapped on Bi- and Trimetallic Titanium(III) Systems.” E.del Horno, J. Jover, M. Mena, A. Pérez-Redondo, C. Yélamos, Chem. Eur. J., 2019, 25, 7096-7100.

DOI: 10.1002/chem.201900083 -- Link 

“Molecular Design of Cyclopentadienyl Tantalum Sulfide Complexes.” M. Gómez, J. I. González-Pérez, C. Hernández-Prieto, A. Martín, M. Mena, C. Santamaría, M. Temprado, Inorg. Chem, 2019, 58, 5593-5602.

DOI: 10.1021/acs.inorgchem.8b03563 -- Link

“The Puzzling Monopentamethylcyclopentadienyltitanium(III) Dichloride Reagent: Structure and Properties.” M. García-Castro, C. García-Iriepa, E. del Horno, A. Martín, M. Mena, A. Pérez-Redondo, M. Temprado, C. Yélamos, Inorg. Chem, 2019, 58, 5314-5324.
DOI: 10.1021/acs.inorgchem.9b00437
 -- Link

“Reactivity of Tuck-over Titanium Oxo Complexes with Isocyanides.” M. Gómez-Pantoja, J.I.González-Pérez, A. Martín, M. Mena, C. Santamaría, M. Temprado, Organometallics, 2018, 37, 2046-2053.
DOI: 10.1021/acs.organomet.8b00212 -- Link

“An Effective Route to Dinuclear Niobium and Tantalum Imido Complexes.” M. Gómez, C. Hernández-Prieto, A. Martín, M. Mena,C. Santamaría, Inorg Chem, 2017, 56, 11681-11687.
DOI: 10.1021/acs.inorgchem.7b01652 -- Link

“Group 4 Half-Sandwich Tris(trimethylsilylmethyl) Complexes: Thermal Decomposition and Reactivity with N,N-Dimethylamine–Borane” M. Greño, E. del Horno, M. Mena, A. Pérez-Redondo, V. Varela-Izquierdo, C. Yélamos, Inorg. Chem., 2017, 56, 11220-11229.
DOI: 10.1021/acs.inorgchem.7b01607 -- Link

“Intermetallic Cooperation in C−H Activation Involving Transient Titanium-Alkylidene Species: A Synthetic and Mechanistic Study.” J. J. Carbo, D. García-López, M. Gómez-Pantoja, J. I. González-Pérez, A. Martín, M. Mena, C. Santamaría, Organometallics, 2017, 3076-3083.
DOI: 10.1021/acs.organomet.7b00416 -- Link

“Isolable zirconium hydride species in the reaction of amido complexes with amine‒boranes.” M. Greño, M. Mena, A. Pérez-Redondo, C. Yélamos, Dalton Trans., 2017,46, 5138 – 5141.
DOI: 10.1039/c7dt00857k -- Link

“Cleavage of Dinitrogen from Forming Gas by a Titanium Molecular System under Ambient Conditions.” M. González-Moreiras, M. Mena, A. Pérez-Redondo, C. Yélamos, Chem. Eur. J., 2017, 23, 3558 – 3561
DOI: 10.1002/chem.201700152 -- Link

“C−H Activation on an Oxo-Bridged Dititanium Complex: From Alkyl to μ-Alkylidene Functionalities.” J. I. González-Pérez, A. Martín, M. Mena, C. Santamaría, Organometallic, 2016, 35, 2488 – 2493.
DOI: 10.1021/acs.organomet.6b00381 -- Link

“Systematic Approach for the Construction of Niobium and Tantalum Sulfide Clusters” M. Gómez, C. Hernández-Prieto, A. Martín, M. Mena, C. Santamaría, Inorg. Chem., 2016, 55, 3815 – 3821.
DOI: 10.1021/acs.inorgchem.5b02816 -- Link 

“Heterometallic Cube-Type Molecular Nitrides” M. Mena, A. Pérez-Redondo, C. Yélamos, Eur. J.Inorg. Chem., 2016, 2016, 1762 – 1778.
Microreview. DOI: 10.1002/ejic.201600135 
-- Link 

 “Homo and Heteropolymetallic Group 4 Molecular Nitrides” J. Caballo, M. Greño, M. Mena, A.Pérez-Redondo, C. Yélamos, Dalton Trans, 2015, 44, 18145-18157. 
DOI: 10.1039/c5dt02836a -- Link

“Carbon-Nitrogen Bond-Construction and Carbon-Oxygen Double Bond-Cleavage on a Molecular Titanium Oxonitride: A Combined Experimental and Computational Study.” J. J. Carbó, D. García-López, O. González-del Moral, A. Martín, M. Mena, C. Santamaría, Inorg. Chem., 2015, 54, 9401-9412.
DOI: 10.1021/acs.inorgchem.5b00943 -- Link

“Heterometallic complexes with cube-type [MTi3N4] cores containing Group 10 metals in a variety of oxidation states.” N. Martínez-Espada, M. Mena, A. Pérez-Redondo, V. Varela-Izquierdo, C.Yélamos, Dalton Trans., 2015, 44, 9782-9794. 
DOI: 10.1039/c5dT01200g -- Link 

“Partial Hydrogenation of a Tetranuclear Titanium Nitrido Complex with Ammonia Borane.” J. Caballo, M. González-Moreiras, M. Greño, M. Mena, A. Pérez-Redondo, C. Yélamos, Inorg Chem, 2014, 53, 8851-8853.
DOI: 10.1021/ic5015972 -- Link

“Reactivity with Electrophiles of Imido Groups Supported on Trinuclear Titanium Systems.” J.Caballo, M. González-Moreiras, M. Mena, A. Pérez-Redondo, C. Yélamos, Inorg. Chem., 2013, 52, 11519-11529.
DOI: 10.1021/ic4018294 -- Link 

“Redox-Active Behavior of the [{Ti(⁵-C5Me5)(-NH)}3(³-N)] Metalloligand” J. Caballo, J. J. Carbó, M. Mena, A. Pérez-Redondo, J.-M. Poblet, C. Yélamos, Inorg Chem., 2013, 52, 6103-6109. 
DOI: 10.1021/ic400463a -- Link

“Contact and solvent-separated ion pair aluminium “ate” complexes on a titanium oxide molecular model.” A. Hernán-Gómez, A. Martín, M. Mena, C. Santamaría, Dalton Trans., 2013, 42, 5076-5084.
DOI: 10.1039/c3dt32725f -- Link

“Copper(I) and Silver(I) Complexes Supported by the Tridentate [{Ti(h⁵-C5Me5)(m-NH)}3(m³-N)] Metalloligand.” A. Martín, N. Martínez-Espada, M. Mena, A. Pérez-Redondo, C. Yélamos, Inorg. Chem., 2013, 52, 918 -930. 
DOI: 10.1021/ic302113k -- Link

“Co-complexation of Lithium Gallates on the Titanium Molecular Oxide [{Ti(h⁵-C5Me5)(m-O)}3(m³-CH)].” M. Gómez-Pantoja, P. Gómez-Sal, A. Hernán-Gómez, A. Martín, M. Mena, C. Santamaría, Inorg. Chem., 2012, 51, 8964-8972.

DOI: 10.1021/ic301057u -- Link

“Electrophilic attack on trinuclear titanium imido-nitrido systems” J. Caballo, M. González-Moreiras, M. Mena, A. Pérez-Redondo, C. Yélamos, Dalton Trans., 2012, 41, 6069-6071. 
DOI: 10.1039/c2dt30486d -- Link

“Lithium Aluminates on a Molecular Titanium Oxide.” A. Hernán-Gómez, A. Martín, M. Mena, C.Santamaría, Inorg. Chem., 2011, 50, 11856-11858.
DOI: 10.1021/ic201838z -- Link

 

“Cadmium and mercury complexes containing trinuclear titanium imido-nitrido metalloligands.” A.Martín, M. Mena, A. Pérez-Redondo, C. Yélamos, Eur. J. Inorg. Chem., 2011, 2011, 5313-5321.
DOI: 10.1002/ejic.201100888 -- Link

 “Discovering the chemical reactivity of the molecular oxonitride [{Ti(⁵-C5Me5)(-O)}3(³-N)].”   S.Aguado-Ullate, J. J. Carbó, O. González-del Moral, M. Gómez-Pantoja, A. Hernán-Gómez, A. Martín, M. Mena, J.-M. Poblet, C. Santamaría, J. Organomet. Chem., 2011, 696, 4011-4017.
DOI:10.1016/j.jorganchem.2011.06.023 -- Link

“Molecular Nitrides with Titanium and Rare-Earth Metals.” J. Caballo, M. García-Castro, A. Martín, M. Mena, A. Pérez-Redondo, C. Yélamos, Inorg. Chem., 2011, 50, 6798-6808.

DOI: 10.1021/ic2008683 -- Link

“Ammonia Activation by μ³-Alkylidyne Fragments Supported on a Titanium molecular Oxide Model.” S. Aguado-Ullate, J. J. Carbó, O. González-Moral, A. Martín, M. Mena, J.-M. Poblet, C.Santamaría, Inorg. Chem., 2011, 50, 6269-6279.
DOI: 10.1021/ic2006327 -- Link

“A new double-cube nitride complex containing titanium and potassium.” A. Martín, M. Mena, A. Pérez-Redondo, C. Yélamos, Acta Crystallographica Section C: Crystal Structure Communications., 2011, C67, m157-m159.

DOI: 10.1107/S0108270111012686

“Cyclopentadienyl and Alkynyl Copper(I) Derivatives with the [{Ti(⁵-C5Me5)(-NH)}3(³-N)] Metalloligand.” N. Martínez-Espada, M. Mena, M. E. G. Mosquera, A. Pérez-Redondo, C. Yélamos, Organometallics, 2010, 29, 6732-6738.

DOI: 10.1021/om100824q -- Link

“Incorporation of Boron, Aluminum and Gallium Derivatives into [{Ti(h⁵-C5Me5)(m-O)}3(³-CR)](R=H, Me).” A. Hernán-Gómez, A. Martín, M. Mena, C. Santamaría, Inorg. Chem., 2010, 49, 8401-8410.
DOI: 10.1021/ic100912p -- Link

“Lewis Base Behavior of Bridging Nitrido Ligands of Titanium Polynuclear Complexes.” J. J. Carbó, N. Martínez-Espada, M. Mena, M. E. G. Mosquera, J.-M. Poblet, C. Yélamos, Chem. Eur. J., 2009, 15, 11619-11631.
DOI: 10.1002/chem.200901598 -- Link 

“Molecular Nitrides with Titanium and Group 13-15 Elements” M. García-Castro, A. Martín, M.Mena, C. Yélamos, Chem. Eur. J., 2009, 15, 7180-7191.
DOI: 10.1002/chem.200900660 -- Link

“Hydron-Transfer Processes Involving an Organotitanium Oxide and Alcohols.” J. J. Carbó, O. González-Moral, A. Martín, M. Mena, J.-M. Poblet, C. Santamaría, Eur. J. Inorg. Chem., 2009, 2009, 643-653. 
DOI: 10.1002/ejic.200801072 -- Link

“Mercury or Silver Atoms Bridging Trinuclear Titanium Imido-Nitrido Systems.” A. Martín, N. Martínez-Espada, M. Mena, M. E. G. Mosquera, A. Pérez-Redondo, C. Yélamos, Chem. Commun., 2008, 6561-6563.
DOI: 10.1039/b814982h -- Link

“Yttrium and Erbium Halide Complexes with [{Ti(⁵-C5Me5)(-NH)}3(³-N)] as a Neutral Tridentate Ligand” J. Caballo, M. García-Castro, A. Martín, M. Mena, A. Pérez-Redondo, C.Yélamos, Inorg. Chem., 2008, 47, 7077-7079
DOI: 10.1021/ic8010426 -- Link

“Construction of Titanasiloxanes by Incorporation of Silanols to the Metal Oxide Model
[{Ti(
⁵-C
5Me5)(-O)}3(³-CR)]: DFT Elucidation of the Reaction Mechanism.” J. J. Carbó, O. González-Moral, A. Martín, M. Mena, J.-M. Poblet,  C. Santamaría, Chem. Eur. J., 2008, 14, 7930-7938.
DOI: 10.1002/chem.200800630 -- Link

“Group 13 Organoderivatives Supported on a Metallic Oxide Model.” O. González-Moral, A. Hernán-Gómez, A. Martín, M. Mena, C. Santamaría, Dalton Trans., 2008, 44-46.
DOI: 10.1039/b716166m -- Link

“Encapsulation of a trinuclear silver(I) cluster by two imido-nitrido metalloligands [{Ti(⁵-C5Me5)(-NH)}3(³-N)].” A. Martín, N. Martínez-Espada, M. Mena, C. Yélamos, Chem. Commun., 2007, 2983-2985.
DOI: 10.1039/b704180b -- Link

“Addition of Terminal Alkynes to a Molecular Titanium-Zinc Nitride.” J. J. Carbó, A. Martín, M. Mena, A. Pérez-Redondo, J.-M. Poblet, C. Yélamos, Angew. Chem. Int. Ed., 2007, 46, 3095-3098.
DOI: 10.1002/anie.200604677 -- Link

“Group 13 and 14 Alkyl Derivatives of the Imido-Nitrido Metalloligand [{Ti(h⁵-C5Me5)(µ-NH)}3(µ³-N)]”. M. García-Castro, A. Martín, M. Mena, C. Yélamos, Organometallics, 2007, 26, 408-416. 
DOI:  10.1021/om060895+ -- Link

“Titanium-alkaline earth molecular oxides as supports of carbanions derived from µ3- ethylidyne Groups”. A. Martín, M. Mena, M. C. Morales-Varela, C. Santamaría, Eur. J. Inorg. Chem. 2006, 2006, 2137-2145. 
DOI: 10.1002/ejic.200600082 -- Link

"Cube-Type nitrido complexes containing Titanium and Zinc/Copper”. A. Martín, N. Martínez-Espada, M. Mena, A. Pérez-Redondo, C. Yélamos, Inorg. Chem., 2006, 45, 6901- 6911. 
DOI: 10.1021/ic0603407 -- Link

“Iodine Attack on the Metalloligand [{Ti(h⁵-C5Me5)(µ-NH)}3(µ³-N)]: Surprising Formation of the [Ti3(h⁵-C5Me5)3I2(µ-NH)3(NH3)]+ Cation”. M. García-Castro, A. Martín, M. Mena, J.-M. Poblet, C. Yélamos, Eur. J. Inorg. Chem., 2006, 1155-1160. 
DOI: 10.1002/ejic.200500840 -- Link

“Amido-bridged double-cube nitrido complexes containing titanium and magnesium/calcium”. A. Martín, M. Mena, A. Pérez-Redondo, C. Yélamos, Dalton Trans., 2005, 2116–2119. 
DOI: 10.1039/B503405A -- Link

“Hydrocarbon species µ³-CCH2-, µ³-CCH3 and µ-CHCH3 supported on Ti3O3”. O. González del Moral, A. Martín, M. Mena, M. C. Morales-Varela, C. Santamaría, Chem. Commun., 2005,3682-3684. 
DOI: 10.1039/B504467G -- Link 

“Synthetic and Theoretical Study of the Incorporation of Metal Halides in [{Ti(h⁵-C5Me5)(µNH)}3(µ³-N)⁺”. M. García-Castro, J. Gracia, A. Martín, M. Mena, J.-M. Poblet, J. P. Sarasa, C.Yélamos, Chem. Eur. J.2005, 11, 1030-1041. 
DOI: 10.1002/chem.200400553 -- Link

“Cube-Type Nitrido Complexes Containing Titanium and Alkali/Alkaline-Earth Metals”. Martín, M. Mena, A. Pérez-Redondo, C. Yélamos, Inorg. Chem., 2004, 43, 2491-2498. 
DOI: 10.1021/ic035493y -- Link

“Deprotonacion of µ³-Methylidyne Groups on a Ti3O3 Support: A Way to Build Oxotitanocubanes Containing Alkali and Alkaline-Earth Metals”. Martín, M. Mena, M. C. Morales-Varela, C. Santamaría, Eur. J. Inorg. Chem., 2004, 1914-1921.
DOI: 10.1002/ejic.200300840 -- Link

“Coordination of [{Ti(h⁵-C5Me5)(µ-NH)}3(µ³-N)] to Metal Cyclopentadienides: Cyclopentadienyl Azaheterometallocubanes”. M. García-Castro, A. Martín, M. Mena, C. Yélamos, Organometallics,  2004, 23, 1496-1500. 
DOI : 10.1021/om030554l -- Link

“Molecular Nitrides Containing Group 4 and 5 Metals: Single and Double-cube molecular nitrido” A. Abarca, M. V. Galakhov, J. Gracia, A. Martín, M. Mena, J.-M. Poblet, J. P. Sarasa, C. Yélamos, Chem.Eur.J., 2003, 9, 2337-2346. 
DOI: 10.1002/chem.200204593 -- Link

“Intercalation of Alcali Metal Cations into Layered Organotitanium Oxides”, J. Gracia, A. Martín, M. Mena, M. C. Morales-Varela, J.-M. Poblet, C. Santamaría, Angew. Chem. Int. Ed.2003, 42,  927-930. 
DOI: 10.1002/anie.200390246 -- Link

“Transfer Hydrogenation Processes to µ³-Alkylidyne Groups on the Organotitanium Oxide [Ti3Cp*3O3]”. R. Andrés, M. V. Galakhov, P. Gómez-Sal, A. Martín, M. Mena, M. C. Morales-Varela, C. Santamaría, Chem. Eur. J., 2002, 8, 805-811. 
DOI: 10.1002/1521-3765(20020215)8:4<805::AID-CHEM805>3.0.CO;2-H -- Link

"Titanium-Group 2 Metal Molecular Nitrides”. A. Martín, M. Mena, A. Pérez-Redondo, C. Yélamos, Organometallics, 2002, 21, 3308-3310. 
DOI: 10.1021/om020379t -- Link

“Rhodium/Iridium-Titanium Azaheterometallocubanes”. K. Freitag, J. Gracia, A. Martín, M. Mena, J.-M. Poblet, J. P. Sarasa, C. Yélamos., Chem. Eur. J., 2001, 7, 3644-3651.
DOI: 10.1002/1521-3765(20010903)7:17<3644::AID-CHEM3644>3.0.CO;2-9 -- Link

“Titanium Alkali Metal Nitrido Complexes”. M. García-Castro, A. Martín, M. Mena, A. Pérez-Redondo, C. Yélamos, Chem. Eur. J., 2001, 7, 647-651.
DOI: 10.1002/1521-3765(20010202)7:3<647::AID-CHEM647>3.0.CO;2-A -- Link

“Ti(h⁵-C5Me5)(µ-NH)}3(µ³-N)]: an efficient entry to single and double cube-type nitrido complexes”, A. Abarca, A. Martín, M. Mena, C. Yélamos, Angew. Chem. Int. Ed., 2000, 39,   3460-3463.
DOI: 10.1002/1521-3773(20001002)39:19<3460::AID-ANIE3460>3.0.CO;2-Y -- Link

“Construction of Heterometallic Cubanes Ti3Cp*3(µ³-CMe)}(µ³-O)3{Mo(CO)3}”. A. Abarca, M.Galakhov, P. Gómez-Sal, A. Martín, M. Mena, J.M. Poblet, C. Santamaría, J. P. Sarasa, Angew. Chem. Int. Ed., 2000, 39, 534- 537. 
DOI: 10.1002/(SICI)1521-3773(20000204)39:3<534::AID-ANIE534>3.0.CO;2-3 -- Link

“Ammonolysis of Mono(pentamethylcyclopentadienyl) Titanium(IV) Derivatives”. A. Abarca, P. Gómez-Sal, A. Martín, M. Mena, J.-M. Poblet, C. Yélamos, Inorg. Chem., 2000, 39, 642-651.
DOI: 10.1021/ic9907718 -- Link